Synthesis and Characterization of Complexes of New Derivative of Cyclopentaphenanthren-3-one with Manganese (II), Iron (II), Cobalt (II), Nickel (II), and Copper (II) Ions


This work involves the chemical preparation from a series of metal Complexes having the general composition M(L)2(H2O)2, where M = [Mn+2, Fe+2, Co+2, Ni+2 and Cu+2].The ligand used was9-fluoro-17-(1-hydrazono-2-hydroxyethyl)-11,17-dihydroxy-10,13,16-trimethyl-6,7,8,9,10,11,12,13,14,15,16,17-dodecahydro-3H-cyclopenta[α]phenanthren-3-one (FHDTCP), who was diagnosed by H-NMR spectra.These complexes have been prepared and characterized by the ligand to metal by molar conductance, spectral (UV-Visible and FT-IR), and atomic absorption studies. The IR spectral measurements forecast interference to oxygen, nitrogen in coordination from the electron pairs to the metal ion in the center. And suggested the complexes geometry be octahedral for all