Preparation, Characterization and Structural Studies of Some Phenyl Isothiocynate Metal Complexes

Abstract

Phenyl isothiocynate complexes of Cu (I), Cu(II), Mn(II), Fe(II), Fe (III),Cr(III) and Ce(III) have been prepared and analyzed spectroscopicaly by Elementalanalyses and atomic absorption technique; the magnetic susceptibility and theconductivity have also been measured and molar ratio of Ligand: Matale with moleratio method and Job Method. From these measurement it is concluded that Cu(I),Fe(III) and Mn(II) form tetrahedral complexes, while Cu (II) Forms square plannercomplexes, and Cr (III) and Ce(III) forms octahedral complexes.