Preparation and Study of Charge- Transfer Complexes for Acetylenic Amine Derivatives


Acetylenic amine derived from secondary amines such as piperidine , pyrolidine anddiethyl amine were synthesized as charge transfer donor have been treated with receptor I2,Br2 andDDQ (DDQ = 2,3-Dichloro-5,6-Dicyano-p-Benzoquinone) to prepare transitional charge complexes .Benesi-Heldbrand equation have been used at (λmax)for formation complexes to calculate potentialionize. Calculation for acetylenic amines derivatives at the first time from transitional energy withstudied receptor and calculated equilibrium constant