@Article{, title={Synthesis, Characterization and Kinetic Study of Monomeric Complexes of Cyclohexane-1, 2- bis (Thiosemicarbazone) with Cobalt (II), Nickel (II) and Copper (II)}, author={Al-Ameen Bariz Omar Ali}, journal={Al-Mustansiriyah Journal of Science مجلة علوم المستنصرية}, volume={28}, number={2}, pages={48-54}, year={2017}, abstract={Cyclohexane-1,2-bis(thiosemicarbazone) (CHTSC) was synthesized via the condensation reactionof cyclohexane-1,2-dione and thiosemicarbazide. Series of metal complexes of the prepared ligand,of general formula [M(CHTSC)(NO3)2], were reported. The prepared coordination complexeswere characterized and their structures elucidated using different techniques. These showedthat all complexes are octahedral geometries. The kinetics of the formation of these complexeshave been investigated using stopped-flow spectrophotometry. These studies revealed that thereactions are completed on the second’s timescale with 1st-order dependence (either on the concentrationof metal salt or on the concentration of CHTSC)

} }