TY - JOUR ID - TI - Synthesis, Molecular Structure from the X-ray Diffraction Data of the Powder (1E,1'E)-1,1'-(1,4-Phenylene)Bis(N-(Adamantan-1-yl)methanimine) AU - Shukkur A. Hamed PY - 2021 VL - 62 IS - 4 SP - 1066 EP - 1076 JO - Iraqi Journal of Science المجلة العراقية للعلوم SN - 00672904 23121637 AB - The title compound was synthesized by condensation between two equivalents adamantan-1-ylamine and one equivalent of benzene-1,4-dicarbaldehyde in n-BuOH and produced a good yield 87% of new bis Schiff base. The compound skeleton was affirmed by FTIR, 1H NMR, LC-MS, and X-ray powder diffraction. The structure was solved by a parallel tempering process and refined by using Rietveld refinement. Two adamantan-1-ylimino groups are connected in the anti-positions to the planar central 1,4-dimethylbenzene group. All rings of the adamantyl group possess normal chair conformation.

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