Sodium – N – (3-mercapto-1,2,4-thiadiazole ) Dithiocarbamate as a Chelating ligand: complexes with Nickel(II), Paladium(II) and Platinium(IV).

Abstract

Chelates of Ni (II), Pd (II) and Pt (IV) with potassium 3-amino-5-mercapto-1,2,4-thiodiazole -diethiocarbamate (TC –K+ (have been prepared. All these chelates have been characterized by thermal analysis (TG-DTA) ,Infra-red (IR) ,(UV/Vis) spectrum Magnetic sensitive and Conductivity measurement .Ni (II) and Pt (IV) chelates are found to have octahedral structures ,while Pd (II) complex may have square planar symmetry.