Reduction of Copoly ( Acrylonitrile – Methyl acrylate),And Grafting The product with Amic Acids
Abstract
Abstract High molecular weight copoly (allyl amine – methyl acrylate ) was prepared for the first time from lithium aluminum hydride reduction of copoly (acrylonitrile – methyl acrylate ) . softening point of the purified copoly(allyl amine – methyl acrylate ) was 280 - 289°C and was obtained in (85%) Conversion . Intrinsic Viscosity of the new copolymer was (1.0)dl/g using DMSO as the solvent . The prepared copoly (allyl amine – methyl acrylate ) was allowed to react with maleic anhydride , and a new Copolymer was formed having Pendant maleamic acid groups. Five other novel Copolymers were prepared by allowing the copoly(allyl amine – methyl acrylate ) to react with succinic , phthalic , glutaric , citraconic ,and itaconic anhydrides . The prepared Coply [N – substituted (allylamine – methyl acrylate) ] resins were characterized using IR ,NMR, elemental analysis and TG and DTGtechniques .
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