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Article
Optical and Optoelectric Properties in PbCdS Ternary Thin Films Deposited by CBD
الخصائص البصرية والكهروبصرية للاغشية الثلاثية PbCdS المرسبة بطريقة الحمام الكيميائي

Authors: J. P. Ponpon --- Ali M. Musa --- Modaffer A. Mohammed
Journal: Engineering and Technology Journal مجلة الهندسة والتكنولوجيا ISSN: 16816900 24120758 Year: 2010 Volume: 28 Issue: 6 Pages: 1050-1060
Publisher: University of Technology الجامعة التكنولوجية

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Abstract

PbxCd1-xS films have been prepared in the composition range of 0.05£ x£0.25by using a chemical bath deposition growth technique under optimum conditionsto deposit good photo response. X-ray diffraction study results show that the filmsare of PbS-CdS composite with individual CdS and PbS planes. The filmsexhibited two direct band gaps, 2.4 eV belongs to CdS, and the second variescontinuously from 2.4eV to 1.3eV. The surface morphology of the films is smoothwith crystallite of increasing grain size with increasing the mole fraction (x). Thedecrease in the band gap with increase in lead concentration suggests that theComposite of PbS (Eg=0.41eV) with CdS (Eg=2.4eV).

x ≤ وبتراكيز تتراوح مابين ( 2.5 (Pbx Cd1-x S ) تم ترسيب غشاء رقيق لمركب0.05 ) باستخدام تقنية الترسيب بالحمام الكيمياوي وباعتماد الضروف المثلى للحصول على ≤يشتمل (PbS-CdS) أستجابية ضوئية جيدة. قياسات حيود الأشعة السينية اضهرت إن المركبeV) المنفردة .اضهرت الأغشية قيمتين لفجوة الطاقة المباشرة (CdS و PbS) على مستويات1.3 ) . سطح الأغشية eV) 2.4 ) إلى eV) 2.4 ) عائدة لكبريتيد الرصاص والثانية تتغير منالنقصان بقيمة فجوة الطاقة .(x) كان صقيل مع زيادة في الحجم الحبيبي بزيادة الكسر المولي. (PbS) و (CdS) مع زيادة تركيز الرصاص يؤدي إلى تكوين مركب من


Article
Influence of Deposition Parameters on Optical and Electrical Properties of CuxS Thin Films Prepared Using Chemical Bath Deposition Method

Authors: A.M. Mousa --- S.H. Nasher --- J.-P. Ponpon
Journal: Iraqi Journal of Applied Physics المجلة العراقية للفيزياء التطبيقية ISSN: 18132065 23091673 Year: 2008 Volume: 4 Issue: 3 Pages: 19-24
Publisher: iraqi society for alternative and renewable energy sources and techniques الجمعية العراقية لمصادر وتقنيات الطاقة البديلة والمستجدة

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Abstract

Thin films of CuxS have been deposited in an aqueous solution of copper chloride, tri ethanol amine, aqueous ammonia and thiourea. The effect of deposition time, solution pH and thiourea amount on films thickness, growth rate, optical and electrical properties has been studied. The film thickness increases with increasing deposition time and thiourea volume, whereas it decreases with increasing the solution pH. The corresponding small modifications of optical properties can be explained by the increase in roughness with film thickness. Electrical resistivity is strongly influenced by the solution pH and by the thiourea amount but depends to a much less extent on the film thickness.

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