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Preparation, Characterization and Structural Studies of Some Phenyl Isothiocynate Metal Complexes

Authors: Asmaa K. Ayal --- Shatha F. Nareen --- Abbas Ali Salih Al-Hamdani
Journal: Engineering and Technology Journal مجلة الهندسة والتكنولوجيا ISSN: 16816900 24120758 Year: 2011 Volume: 29 Issue: 2 Pages: 253-260
Publisher: University of Technology الجامعة التكنولوجية

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Abstract

Phenyl isothiocynate complexes of Cu (I), Cu(II), Mn(II), Fe(II), Fe (III),Cr(III) and Ce(III) have been prepared and analyzed spectroscopicaly by Elementalanalyses and atomic absorption technique; the magnetic susceptibility and theconductivity have also been measured and molar ratio of Ligand: Matale with moleratio method and Job Method. From these measurement it is concluded that Cu(I),Fe(III) and Mn(II) form tetrahedral complexes, while Cu (II) Forms square plannercomplexes, and Cr (III) and Ce(III) forms octahedral complexes.

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